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Yes, you can use cornstarch to bread chicken, though from my research, you usually have to use it in combination with something like breadcrumbs. If you try to use only cornstarch, you tend to have inconsistent results as cornstarch is normally used as a thickner for gravys, sauces, and soups.
Yes, you can use cornstarch to bread chicken. If you've ever tried the gluten-free Spicy Chicken at Pei Wei, that is what they coat the crispy chicken for that dish. It makes a light, crispy breading and is an excellent substitute for a gluten free diet.